Supposedly you get better performance when installing DDR in pairs, but as Dar13 pointed out, DDR3 does not mean triple channel. It's only supported by a few i7's and Xeons, see
here. Basically, your most common CPUs right now will likely not support triple channel, unless the motherboard has a chipset that can add support to that (I don't know for sure).
Also, if you buy any package of ram that says triple channel ram kit, the only thing different about it over other sticks is the fact you're getting 3 in a single package. It's the same ram.
DDR3 is better than DDR2; it's faster and it's the current standard and will likely be cheaper. The i-core series of CPUs use DDR3 simply because it's newer and better. Why make a new chip use old technology?
Buy 4 sticks if you need it, but if you're happy with 8GB then just get 2x4GB sticks. I have 16GB total myself.
"You're all wrong. You're all idiots." ~Fluffy Rabbit