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will i beable to use a toon shader like in XIII by UBI Soft

That's a hard question to answer. While we have access to Pixel Shaders, we really don't have full control as far as I can tell. It's possible you could create the .fx files required to make it appear as toon shading, but not sure if it would look quite right. What you might want to try to get a toon look for your models is to create the Textures with a Bold Black Line around the outline. That might give a little bit what you want but wouldn't be the same as the toon shader.
Hopefully Lee or Rich can clear this up some more for us. Also, FPSCreator in it's current state doesn't run as fast. Heavy usage of shaders would cause it to slow down. Time will tell though.
SoulMan

XIII doesn't really *USE* shaders, vertex or pixel, at ALL.

It actually renders each model several times. The outline is generated using the same trick I used to use (and still do) in DBC, where you essentially clone a model, invert the cloned copy, and colour it black.

Thanks to scaling it as a negative number, the Z-buffer places it behind any object that's inside the clone, resulting in the ''outline'' not actually obscuring the gun itself.

Mind you, I saw some code for a combined pixel & vertex shader on GameDev.net somewhere that made some pretty neat cel-shading..